(Z)-3-(4-Bromo­phen­yl)-2-[(2-phenyl­cyclo­hex-2-en-1-yl)imino]-1,3-thia­zol­idin-4-one

نویسندگان

  • Chin Wei Ooi
  • Hoong-Kun Fun
  • Ching Kheng Quah
  • Murugan Sathishkumar
  • Alagusundaram Ponnuswamy
چکیده

The title compound, C(21)H(19)BrN(2)OS, exists in a cis conformation with respect to the N=C bond [1.2602 (14) Å]. The cyclo-hexene ring adopts a distorted half-chair conformation and the C-N bond lies in an equatorial orientation. The thia-zolidine ring forms dihedral angles of 53.76 (7) and 57.22 (7)° with the benzene and bromo-substituted benzene rings, respectively. The dihedral angle between the benzene and bromo-substituted benzene rings is 76.06 (7)°. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(14) loops. The crystal is further consolidated by weak C-H⋯π inter-actions.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012